Question 1Multiple choiceThermal physics & ideal gases
A rigid, sealed container holds 0.050 mol of an ideal monatomic gas at a temperature of 300 K and a pressure of Pa. The gas is heated until its temperature is 400 K. Take J mol⁻¹ K⁻¹. How much thermal energy is transferred to the gas during the heating?
- A.
0 J
- B.
42 J
- C.
104 J
- D.
62 J
Worked solution
Apply the first law of thermodynamics, , where is the work done by the gas.
The container is rigid, so the volume does not change and the gas does no work: . All of the thermal energy supplied therefore goes into internal energy, .
For an ideal monatomic gas the internal energy is entirely the translational kinetic energy of the molecules, , so
The initial pressure is not needed for the energy calculation; it would only be needed to find the final pressure, which rises to Pa because is constant at fixed volume.
The tempting answer 0 J confuses zero work with zero heat: the gas does no work, but it certainly gains energy, as the temperature rise shows. 42 J is , which is the work done in a constant-pressure expansion, not the change in internal energy; 104 J is , the heat needed at constant pressure, where the gas would also expand and do work.