Question 1Multiple choiceWater and Wastewater
A wastewater sample has a 5-day biochemical oxygen demand (BOD₅) of 180 mg/L at 20°C. The BOD reaction rate constant for the sample is 0.23 d⁻¹ (base e). Assuming first-order BOD kinetics, what is the ultimate carbonaceous BOD, , of the sample?
- A.
123 mg/L
- B.
194 mg/L
- C.
263 mg/L
- D.
568 mg/L
Worked solution
With first-order kinetics, the BOD exerted after days is the fraction of the ultimate demand that has been oxidised by then:
The base-e form is used because the rate constant is stated as a base-e value.
Evaluate the fraction exerted at 5 days:
So 68.3% of the ultimate demand is exerted in the first 5 days. Solve for :
The ultimate BOD is larger than the 5-day BOD, as it must be, since 83 mg/L of demand remains to be exerted after day 5.
L₀ ≈ 263 mg/L (option C)
The most tempting wrong answer is B (194 mg/L), which uses with the base-e constant. The base-10 form is valid only with a base-10 constant, which would be d⁻¹ and would give the same 263 mg/L. Option A (123 mg/L) multiplies by instead of dividing, and produces an ultimate BOD smaller than the 5-day BOD, which is impossible. Option D (568 mg/L) divides by , the fraction remaining, instead of the fraction exerted.